Water triage

My kit says 0.25 ppm. Is that dangerous?

It depends, and not on anything your test kit can tell you. A liquid kit measures total ammonia, but only the un-ionised fraction is really toxic — and that fraction is governed by pH and temperature. Each whole pH unit multiplies it roughly tenfold.

So the same 2 ppm reading can be nearly harmless in one tank and lethal in another. This works out which one you are in.

The toxic fraction at common readings

Freshwater. Find your pH, read across to your temperature, and multiply your kit's total-ammonia reading by that percentage — the result is the free ammonia, and it is the only part of the reading that harms fish. Saltwater runs a little higher; the calculator applies that offset for you.

pH 6.520 °C: 0.1% · 25 °C: 0.2% · 30 °C: 0.3%
pH 7.020 °C: 0.4% · 25 °C: 0.6% · 30 °C: 0.8%
pH 7.520 °C: 1.2% · 25 °C: 1.8% · 30 °C: 2.5%
pH 8.020 °C: 3.8% · 25 °C: 5.4% · 30 °C: 7.4%
pH 8.520 °C: 11.1% · 25 °C: 15.2% · 30 °C: 20.2%

What the bands mean

LowAny detectable ammonia in a stocked tank still means the biological filter is not keeping up. Find out why.
under 0.02 ppm
AlertEnough to stress fish over time and damage gill tissue with repeated exposure.
under 0.05 ppm
AlarmActively harmful. Act today, not tomorrow.
under 0.2 ppm
ToxicThis is in the range that kills. Act now.
0.2 ppm and over

The bands are free ammonia (NH3), not the total your kit prints. A 2 ppm total reading is Alarm at pH 8 and Low at pH 7, both at 25 °C.

How this is calculated

A liquid test kit measures total ammonia nitrogen — ammonium (NH4+) plus free ammonia (NH3) together. Only the free form crosses the gill readily, and the split between them is set by pH and temperature, not by how much ammonia is present.

The fraction is 1 / (1 + 10^(pKa - pH)), with pKa from the Emerson et al. (1975) relationship pKa = 0.09018 + 2729.92 / T, T in kelvin. Each whole pH unit changes the free fraction roughly tenfold, which is why the same reading is harmless in one tank and lethal in another.

For saltwater the calculator subtracts 0.08 from pKa as an approximation of the salinity effect. It is not exact, and it errs toward reporting more free ammonia rather than less. The table above is the freshwater relationship.

What this does not model: nitrite, which is separately toxic and is not measured here; species sensitivity, which varies widely; how long the exposure has already lasted; and the accuracy of your test kit, which for strips is poor. If the fish look distressed, act on the fish, not on the arithmetic.

Emerson et al. (1975), aqueous ammonia equilibrium — pKa relationship Checked 2026-08-30.
Keep going

158 care guides, same data

Every number these tools use comes from the species guides — read the one for your animal.

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